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The First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis

✍ Scribed by Kai C. Hultzsch; Jesper A. Jernelius; Amir H. Hoveyda; Richard R. Schrock


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
144 KB
Volume
114
Category
Article
ISSN
0044-8249

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Polymeric catalysts for chemo- and enant
✍ Binod B. De; Braj B. Lohray; Swaminathan Sivaram; Pradeep K. Dhal πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 177 KB πŸ‘ 2 views

Polymeric analogs of well-known chiral Mn(III)-salen complexes were synthesized and were used as recyclable catalysts for asymmetric epoxidation of olefins. For this purpose two different monomers, 2 and 3, bearing chiral Mn(III)-salen moieties were synthesized. The monomer 3 carries a bulky substit