A novel and efficient synthesis of cyclic and acyclic 1,5-alkadiynes by selective coupling of Co2(CO)6-complexed propargyl radicals
β Scribed by Gagik G. Melikyan; Richard C. Combs; John Lamirand; Masood Khan; Kenneth M. Nicholas
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 292 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
N-Alkyl carbamates were obtained with good to excellent yields by clean and mild transcarboxylation of several amines with the previously synthesized DBU-CO 2 complex and subsequent O-alkylation. Transcarboxylation was found to be selective, as only carbamate was formed from 1-hydroxy-2-aminobutanol
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