A new synthetic route to symmetrical photochromic diarylperfluorocyclopentenes
โ Scribed by Linda N. Lucas; Jan van Esch; Richard M. Kellogg; Ben L. Feringa
- Book ID
- 104260625
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 166 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Symmetrical and photochromic diarylperfluorocyclopentene has been prepared by reaction of 3-1ithio-5-chloro-2-methylthiophene with the ethyl ester of hexafluoroglutaric acid, followed by ring closure via a McMurry coupling. Compound 7 is a versatile intermediate for the development of photochromic materials.
๐ SIMILAR VOLUMES
The first total synthesis of (+)-perhydrohistrionicotoxin (I), a useful neurotoxin, 1 was recently reported from these Laboratories. 2,3 We now describe a new, efficient and stereocontrolled route which leads to (t)-perhydrohistrionicotoxin