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A new synthetic entry into the tricyclo[3.3.0.03,7] octane skeleton

✍ Scribed by P Camps; C Iglesias; R Lozano; M.A Miranda; M.J Rodrǐguez


Book ID
108382752
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
174 KB
Volume
28
Category
Article
ISSN
0040-4039

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We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV)