A new synthetic entry into the tricyclo[3.3.0.03,7] octane skeleton
✍ Scribed by P Camps; C Iglesias; R Lozano; M.A Miranda; M.J Rodrǐguez
- Book ID
- 108382752
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 174 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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Received rn US& 14 Elay 1915: received III UK for publlcatlon 10 June 1075) Recently, Roberts described extension of a reaction, first reported by Mitch and Dreiding,' by which exo-2-bromobicyclo[3.2.O]heptan-6-ones, 1, are transformed by base -
We wish to report the synthesis of tricyclo[3.3.0.03'7 ]octane (I) by a structurally unambiguous route and to describe the ring expansion of the derived carbinols II and III. Hydrocarbon I, for which we suggest the trivial name %isnoradamantane", may be regarded as a lower homolog of adamantane (IV)