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A New Synthetic Approach to Forskolin: Construction of the ABC Ring System from d -Galactose

โœ Scribed by Hanna, Issam; Wlodyka, Philippe

Book ID
126212157
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
181 KB
Volume
62
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: A New Synthetic App
ChemInform Abstract: A New Synthetic Approach to Forskolin: Construction of the ABC Ring System from D-Galactose.
โœ I. HANNA; P. WLODYKA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 37 KB ๐Ÿ‘ 2 views

The functionalized tricyclic framework (XI) of the diterpene forskolin is synthesized by an intramolecular Diels-Alder reaction of the dienyne (VII), which is obtained by stereoselective introduction of the C side chains at C-1 and C-2 of tri-O-acetyl-D-galactal (I) via C-Ferrier and Claisen-Ireland

A synthetic approach to the tricyclic sy
A synthetic approach to the tricyclic system of forskolin from D-galactose
โœ Issam Hanna; Jean-Yves Lallemand; Philippe Wlodyka ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 319 KB

The syntksis of tk mkydic system offorskolin by an intramolecular DieleAidcr reaction is described, smrdng from tnQ9-acetyl-D-gakactai. Forskolln. a highly oxygenated labdane diterpcne, exhibits a broad range of physiological activities through its ability to activate adenylate cyclase. The therape