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A New Synthesis of Unsymmetrical Phosphinic Acids

✍ Scribed by Freedman, Leon D.; Doak, G. O.


Book ID
127199340
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
277 KB
Volume
74
Category
Article
ISSN
0002-7863

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This letter describes a method for the synthesis of unsymmetrical phosphinic acids by the phosphinylation of a resin-bound aldehyde and subsequent 'P' alkylation. This synthetic transformation is very difficult to perform as selectively in solution and therefore further exemplifies the powerful natu