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A new synthesis of chlorosulfonyl chlorides

✍ Scribed by E. J. Goethals; M. Verzele

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
329 KB
Volume
74
Category
Article
ISSN
0037-9646

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✦ Synopsis

y-and a-hydroxyalkane-1-thiols, in many cases easily accessible over the chlorohydrins, are converted to y-and a-chloroalkylsulfonyl chlorides by the combined action of chlorine and water. A mechanism is suggested. This new synthesis method provides an easy way to obtain sultams.

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