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A new synthesis of alkane and polyfluoroalkanesulfonyl chlorides

✍ Scribed by Zohra Benfodda; Franck Guillen; Hélène Arnion; Abdelkader Dahmani; Hubert Blancou

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
129 KB
Volume
20
Category
Article
ISSN
1042-7163

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✦ Synopsis

This study describes a new and advantageous procedure for the synthesis of alkanesulfonyl chlorides (2) by the reaction of alkyl thiocyanates (1) with sulfuryl chloride in a mixture of acetic acid and water. The alkanesulfonyl chlorides were obtained in good yields.

📜 SIMILAR VOLUMES

A new synthesis of chlorosulfonyl chlori
A new synthesis of chlorosulfonyl chlorides
✍ E. J. Goethals; M. Verzele 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 329 KB

y-and a-hydroxyalkane-1-thiols, in many cases easily accessible over the chlorohydrins, are converted to y-and a-chloroalkylsulfonyl chlorides by the combined action of chlorine and water. A mechanism is suggested. This new synthesis method provides an easy way to obtain sultams.