A New Structural Class of Lanthanide Carbonates: Synthesis, Properties, and X-ray Structure of the One-Dimensional Chain Complex [Co(NH 3 ) 6 ] 6 [K 2 (H 2 O) 10 ]-[Nd 2 (CO 3 ) 8 ] 2 ·20H 2 O
✍ Scribed by Bond, Deborah L.; Clark, David L.; Donohoe, Robert J.; Gordon, John C.; Gordon, Pamela L.; Keogh, D. Webster; Scott, Brian L.; Tait, C. Drew; Watkin, John G.
- Book ID
- 120637584
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 59 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHÁ Á ÁF interactions w
OH), .4H,O was prepared by digesting Co,(OH),CO, .xH,O in water solution of NH,HCO,. Chemical analyses, diffuse reflectance spectroscopy and XRD data proved that this compound, like Na,Co,(CO,),(OH), . 6H,O and K,Co,(CO,),(OH), .4H,O, is a derivative of the kambaldaite Na