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A new strategy for the synthesis of spiro ketals

โœ Scribed by Danishefsky, Samuel J.; Pearson, William H.

Book ID
126844972
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
292 KB
Volume
48
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

A new strategy for the synthesis of spir
A new strategy for the synthesis of spiro[4,5]decanes: A formal total synthesis of acorone
โœ P.John Biju; G.S.R.Subba Rao ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 145 KB

A new strategy for the construction of spiro [4,5]decanes is described and involves a bridgehead substitution of a methoxyl group in 6 by a methyl group, followed by an oxidative cleavage resulting in a stereogenic spirocentre which culminated in the formal synthesis of acorone.