## Abstract Starting from ethyl 2βcyclohexenβ1βcarboxylate (**3**) the total synthesis of the perhydrohistrionicotoxin intermediate **23** was achieved in 25% overallβyield. The two key steps involve a positionally specific addition of HOBr to the oximeβolefin **7** and the alkylation of bromooxime
β¦ LIBER β¦
A new stereoselective synthetic route to perhydrohistrionicotoxin
β Scribed by Toshiro Ibuka; Yoshinori Mitsui; Kenji Hayashi; Hiroyuki Minakata; Yasuo Inubushi
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 240 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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