A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes
β Scribed by Lautens, Mark; Rovis, Tomislav
- Book ID
- 127212918
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 167 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
In the cyclisation of the diazo-compound (7) to give the diastereomerit pair of lH-2,3\_benzodiazepines (8) and ( 9), alkoxy groups, when present as the medium sized group M, show the opposite effect in promoting face selectivity to that of alkyl groups and the alkoxide ion. Thus when M=OMe the ( 8
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