Metalated heterocycles in the synthesis of ellipticine analogs. A new route to the 10H-pyrido[2,3-b]carbazole ring system
β Scribed by Gribble, Gordon W.; Fletcher, Gillian L.; Ketcha, Daniel M.; Rajopadhye, Milind
- Book ID
- 111675225
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 899 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Aryl-substituted tricarbonyl(rl4-cyclohexa -1,3-diene)iron complexes are oxidatively cyclized in protic medium in the air to tricarbonyliron-complexed 4a,9a-dihydro-9H-carbazoles. The method is applied to the total synthesis of mukonine and mukonidine.
Transition-Metal Complexes in Organic Synthesis. Part 36. Cyclization of Tricarbonyliron Complexes by Oxygen to 4a,9a-Dihydro-9Hcarbazoles: Application to the Synthesis of Mukonine, Mukonidine, and Pyrido(3,2,1-jk)carbazoles. -A novel method for the cyclization of aryl-substituted iron complexes su