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A new route to 2,3,5,6-tetrafluoroterephthal aldehyde and its chemical transformation

✍ Scribed by Shizheng Zhu; Jingwei Zhao; Xian Cai


Book ID
108170259
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
98 KB
Volume
125
Category
Article
ISSN
0022-1139

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A new, three-stage synthesis of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) has been developed which avoids the use of halogenated precursors or reagents. The starting material, 1,3,5trihydroxy-benzene, is converted via the sequence nitrationalkylation-amination to TATB in an overall yield of 87%. T