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New Synthetic Routes to 3-, 5-, and 6-Aryl-2-chloropyridines

✍ Scribed by Church, Robert; Trust, Ronald; Albright, J. Donald; Powell, Dennis


Book ID
111972400
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
1004 KB
Volume
60
Category
Article
ISSN
0022-3263

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A new, three-stage synthesis of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) has been developed which avoids the use of halogenated precursors or reagents. The starting material, 1,3,5trihydroxy-benzene, is converted via the sequence nitrationalkylation-amination to TATB in an overall yield of 87%. T