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A New Reaction for the Direct Conversion of 4-Azido-4-deoxy- d -galactoside into a 4-Deoxy- d - e rythro -hexos-3-ulose

✍ Scribed by Xue, Jie; Wu, Jian; Guo, Zhongwu


Book ID
118049532
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
124 KB
Volume
6
Category
Article
ISSN
1523-7060

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## Abstract The stereoselective reduction of methyl 4,6‐__O__‐benzylidene‐3‐[bis(methylthio)methylene]‐3‐deoxy‐α‐D‐__erythro__‐hexopyranosid‐2‐ulose 1 with sodium tetrahydridoborate and tributyltin hydride, respectively, to (Z)‐configured 4 is described. The increased reactivity of 4 compared to 1