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ChemInform Abstract: A New Approach to C-Branched Monosaccharides by the Stereoselective Hydrodesulfurization of Methyl 4,6-O-Benzylidene-3-(bis(methylthio) methylene)-3-deoxy-α-D-erythro-hexopyranosid-2-ulose.

✍ Scribed by K. PESEKE; G. THIELE; M. MICHALIK


Book ID
112023872
Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
26
Category
Article
ISSN
0931-7597

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A new approach toC-branched monosacchari
✍ Peseke, Klaus ;Thiele, Gabriela ;Michalik, Manfred 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 486 KB

## Abstract The stereoselective reduction of methyl 4,6‐__O__‐benzylidene‐3‐[bis(methylthio)methylene]‐3‐deoxy‐α‐D‐__erythro__‐hexopyranosid‐2‐ulose 1 with sodium tetrahydridoborate and tributyltin hydride, respectively, to (Z)‐configured 4 is described. The increased reactivity of 4 compared to 1