A new approach toC-branched monosacchari
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Peseke, Klaus ;Thiele, Gabriela ;Michalik, Manfred
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Article
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1995
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John Wiley and Sons
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English
⚖ 486 KB
## Abstract The stereoselective reduction of methyl 4,6‐__O__‐benzylidene‐3‐[bis(methylthio)methylene]‐3‐deoxy‐α‐D‐__erythro__‐hexopyranosid‐2‐ulose 1 with sodium tetrahydridoborate and tributyltin hydride, respectively, to (Z)‐configured 4 is described. The increased reactivity of 4 compared to 1