A new method of synthesis of methylN-Boc-2,3-dehydropyrrolidine- and piperidine-2-carboxylates
✍ Scribed by V. S. Kublitskii; A. E. Stepanov; V. M. Trukhan
- Book ID
- 111464724
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2008
- Tongue
- English
- Weight
- 171 KB
- Volume
- 44
- Category
- Article
- ISSN
- 1070-4280
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📜 SIMILAR VOLUMES
The relative stereochemistry of methyl 6-oxo-5-(5-phenyltetrazol-2-yl)piperidine-2-carboxylate, C 14 H 15 N 5 O 3 , has been determined. It con®rms the cis con®guration of the piperidine ring as well as the position of the substituent on the tetrazole ring. The packing of the molecules is in¯uenced
A one-pot approach to 6-membered heterocyclic rings combines two 1,3-dipole equivalents: P-azaallyl anions (2) and iodosilane 3. The resulting a-2.6.disubstituted 4methylenepiperidines are converted in high yield to 2,4,6\_trisubstituted pyridines (6) by oxidation with mercuric acetate in acetic aci