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A new method for investigating the mechanism of initiation of radical polymerization

✍ Scribed by Ezio Rizzardo; David H. Solomon


Publisher
Springer
Year
1979
Tongue
English
Weight
269 KB
Volume
1
Category
Article
ISSN
0170-0839

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πŸ“œ SIMILAR VOLUMES


The mechanism of initiation in the free
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The reactions of N-vinylcarbazole and of N-vinylpyrrolidone with benzoyl peroxide and with di-t-butyl peroxalate in the presence of the nitroxide scavenger l,l,3,3-tetramethyl-l,3-dihydroisoindol-2yloxyl are reported. Use of di-t-butyl peroxalate leads to the expected radical intermediates which are

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The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of ethoxyl radicals with methyl methacrylate and with styrene. The reaction of isopropoxyl radicals with styrene is also reported. The major pathway in all cases was addition to the uns

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✍ J. Jakubiak; X. Allonas; J.P. Fouassier; A. Sionkowska; E. Andrzejewska; L.Γ…. Li πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 186 KB

Results of the camphorquinone/hindered piperidines, visible-light photoinduced polymerization of triethyleneglycol dimethacrylate are presented. The effectiveness of piperidines as a coinitiator is compared with a few aliphatic amines and aromatic amines. The main objective in this research was to s