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New initiator systems for radical polymerization of vinyl monomers

โœ Scribed by Otsu, Takayuki ;Yamaguchi, Masami ;Takemura, Yasuhiko ;Kusuki, Yoshihiro ;Aoki, Shuzo


Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
171 KB
Volume
5
Category
Article
ISSN
0449-2986

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Almtract--It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products