Polymerization of vinyl monomers by organoaluminum initiators
β Scribed by Wexler, Herman ;Manson, John A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1965
- Tongue
- English
- Weight
- 633 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0449-2951
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π SIMILAR VOLUMES
Almtract--It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products
## Abstract The polymerization of vinyl monomers, mainly styrene and methyl methacrylate, initiated by zwitterionic poly[3βdimethyl(methacryloyloxyβethyl)ammonium propane sulfonate], [poly(DMAPS)], in aqueous solution was studied under vacuum at 85Β°C. An initiation mechanism involving hydrogen atom