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A new method for fluorination of sterols

✍ Scribed by Shlomo Rozen; Yonah Faust; Hadassah Ben-Yakov


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
198 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis


Diethylaminosulfurtrifluoride (DAST) is a good fluorinating reagent for sterols. The fluorinating reactions proceed through SN2 mechanism, while reactions through free carbonium ion are responsible for rearrangements and eliminations.


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