A new mechanistic proposal for the origin of α-homoallylic alcohols in indium-mediated allylation reactions in water
✍ Scribed by Teck-Peng Loh; Kui-Thong Tan; Qi-Ying Hu
- Book ID
- 104231929
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 136 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
1,1-Trifluoro-4-bromobut-2-ene / Aldehydes / Tin / Indium / Water The indium-mediated allylation reaction of aldehydes with 4-high regio-and excellent diastereoselectivities were obtained. bromo-1,1,1-trifluoro-2-butene in water afforded β-trifluoromethylated homoallylic alcohols in high yields. In
Linear a homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this p
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