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A New Iron-Mediated Strategy for the Synthesis of α-Lipoic Acid and Analogues

✍ Scribed by Christophe Crévisy; Benjamin Herbage; Marie-Laure Marrel; Loïc Toupet; René Grée

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
368 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis

α-Lipoic acid / Structural analogues / Tricarbonyl(η 5 -pentadienyl)iron cations / Carbonyliron complexes / Diimide reduction Dithioester 10 was synthesized in 6 steps from tricarbonyl-also be of interest for the preparation of various labelled compounds and structural analogues. (diene)iron complex 3. Compound 10 is not only a key intermediate for the synthesis of methyl lipoate (13) but could

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