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A New Family of Modular Chiral Ligands for the Catalytic Enantioselective Reduction of Prochiral Ketones

✍ Scribed by Puigjaner, Cristina; Vidal-Ferran, Anton; Moyano, Albert; Pericàs, Miquel A.; Riera, Antoni


Book ID
127013840
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
164 KB
Volume
64
Category
Article
ISSN
0022-3263

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Chiral thiourea as ligand for the asymme
✍ François Touchard; Patrick Gamez; Fabienne Fache; Marc Lemaire 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 265 KB

The catalytic enantioselective reduction of prochiral ketones using a chiral thiourea as ligand is reported. Several metallic precursors were tested. e.e.'s up to 94% are obtained with a ruthenium complex.