A New Enantiospecific Synthesis of α-Santalanes via Homofragmentation of 1,4-Diol Monosulfonate Esters
✍ Scribed by Bastiaansen, Petrus M. F. M.; Wijnberg, Joannes B. P. A.; de Groot, Aede
- Book ID
- 126899912
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 156 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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## Base-Induced Rearrangement of Perhydronaphthalene-1,4-diol Monosulfonate Esters to 11-Oxatricyclo[5.3.1.0 2,6 ]undecanes. Total Synthesis of Furanether B. -In the presence of LiAlH(O-tBu) 3 the mesylate (I) is found to undergo selective rearrangement to the tricyclic derivative (II). This rear
## Abnticx : A MW 6ynthend 04 ~2-buttnotidti ih de.bcLbcd which .&o&m h.kt&Oh&Lc-Live condenntion 06 an cx-htiyt uteh anion ukth an cu-hetoacefal. Unsaturated five membered ring lactones, butenolides, occur widely in nature and display a wide range of interesting properties (1). Despite the great