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ChemInform Abstract: A New Enantiospecific Synthesis of α-Santalanes via Homofragmentation of 1,4-Diol Monosulfonate Esters.

✍ Scribed by P. M. F. M. BASTIAANSEN; J. B. P. A. WIJNBERG; A. DE GROOT


Book ID
112041101
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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## Base-Induced Rearrangement of Perhydronaphthalene-1,4-diol Monosulfonate Esters to 11-Oxatricyclo[5.3.1.0 2,6 ]undecanes. Total Synthesis of Furanether B. -In the presence of LiAlH(O-tBu) 3 the mesylate (I) is found to undergo selective rearrangement to the tricyclic derivative (II). This rear