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Base-induced and -directed elimination and rearrangement of perhydronaphthalene-1,4-diol monosulfonate esters. Total synthesis of (.+-.)-alloaromadendrane-4.beta.,10.alpha.-diol and (.+-.)-alloaromadendrane-4.alpha.,10.alpha.-diol

โœ Scribed by Jenniskens, Louis H. D.; Wijnberg, Joannes B. P. A.; De Groot, Aede


Book ID
127050284
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
1003 KB
Volume
56
Category
Article
ISSN
0022-3263

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โœ R. P. L. BELL; A. SOBOLEV; J. B. P. A. WIJNBERG; A. GROOT ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 42 KB

## Base-Induced Rearrangement of Perhydronaphthalene-1,4-diol Monosulfonate Esters to 11-Oxatricyclo[5.3.1.0 2,6 ]undecanes. Total Synthesis of Furanether B. -In the presence of LiAlH(O-tBu) 3 the mesylate (I) is found to undergo selective rearrangement to the tricyclic derivative (II). This rear