The extensive bands observed from the hehum afterglow reaction of SO\* m the 250-540 mn region are assigned to the new SO+(A \*rt--X\*l$) system produced from the He\*/S02 dissociative charge-transfer reaction at themA energy. They had been erroneously mterpreted as the SO; (c-4 system produced from
A new emission produced from sulfur monochloride in a helium afterglow: S+2(A2Πu-X2Πg,r)
✍ Scribed by Masaharu Tsuji; Isao Murakami; Yukio Nishimura
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 304 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The $(A 211u-X *I%& emission band system was observed and viirationally analyzed in the 350-670 nm spectral range from a flowmg hehum afterglow study of the S$lz reactlon. Molecular constants for the $(A*& X *llgs) states were determined and compared unth reported photoelectron data.
📜 SIMILAR VOLUMES
Magnetic field effects on the emission intensity were studied for the NO/3 bands in an afterglow produced by a microwave discharge of a N 2 -02 mixture. The (0, v") bands were quenched remarkably by an external magnetic field below 1.8 T, while the (1, o") and (2, v") bands were slightly intensified
Branching fractions are determined for the product NO (A 'X+, u= 0,l) and NO( B 'II, v= 0) emissions as a function of v' in the energy transfer reaction N,(A 'Z:, v') tNO(X 211n v"=O) in a rapidly pumped discharge-flow reactor operated at a total 2 pressure of TC 2 Torr at % 295 K. Using the NO( A Z