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A new diene synthesis via organopalladium chemistry

โœ Scribed by Trost, Barry M.; Fortunak, Joseph M.

Book ID
127059967
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
406 KB
Volume
102
Category
Article
ISSN
0002-7863

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Mercury in organic chemistry. 27. ฯ€-ally
Mercury in organic chemistry. 27. ฯ€-allylpalladium synthesis via organopalladium additions to nonconjugated dienes
โœ Richard C. Larock; Kentaro Takagi ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

=fF A variety of organomercurials react regioselectively with 1,4-, 1,5-and 1,6dienes and i2PdC14 to form good yields of T-allylpalladium colnpounds. These reactions apparently proceed by organopalladium addition to one of the diene double bonds and subsequent palladium migration.