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Enol thioethers in synthesis. Regiocontrolled arylation via organopalladium chemistry

โœ Scribed by Trost, Barry M.; Tanigawa, Yoshio


Book ID
127372300
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
321 KB
Volume
101
Category
Article
ISSN
0002-7863

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Mercury in organic chemistry. 27. ฯ€-ally
โœ Richard C. Larock; Kentaro Takagi ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

=fF A variety of organomercurials react regioselectively with 1,4-, 1,5-and 1,6dienes and i2PdC14 to form good yields of T-allylpalladium colnpounds. These reactions apparently proceed by organopalladium addition to one of the diene double bonds and subsequent palladium migration.