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Mercury in organic chemistry. 27. π-allylpalladium synthesis via organopalladium additions to nonconjugated dienes

✍ Scribed by Richard C. Larock; Kentaro Takagi

Book ID: 104219983
Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 194 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86012-8

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✦ Synopsis

=fF A variety of organomercurials react regioselectively with 1,4-, 1,5-and 1,6dienes and i2PdC14 to form good yields of T-allylpalladium colnpounds. These reactions apparently proceed by organopalladium addition to one of the diene double bonds and subsequent palladium migration.

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