A New Asymmetric Formylation of Aldehydes
✍ Scribed by Dr. Andreas Kirschning; Gerald Dräger; Alexander Jung
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 383 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
dence for the rearrangement (2)+( 7). However, this isomerization can also be detected when (la) is used as starting material: Thus, on reaction of (la) with 6 equivalents of potassium tert-butoxide in THF at 35"C, the enol ether (10) is obtained in 44% yield. Its formation can be explained in terms
## 903-919. [13] The simulations for 1 were performed according to the published procedure [12] with a temperature parameter of 303 K and 2 x lo6 macro steps. Maximum step lengths were 20" ($), 20" ($). 25' (w), and 2.5" (T = C1'-01'-C6), leading to an overall acceptance ratio of 0.48.