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A New Asymmetric Formylation of Aldehydes

✍ Scribed by Dr. Andreas Kirschning; Gerald Dräger; Alexander Jung


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
383 KB
Volume
36
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


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dence for the rearrangement (2)+( 7). However, this isomerization can also be detected when (la) is used as starting material: Thus, on reaction of (la) with 6 equivalents of potassium tert-butoxide in THF at 35"C, the enol ether (10) is obtained in 44% yield. Its formation can be explained in terms

Scalemic 2-Formyl-3-hydroxy[2.2]paracycl
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## 903-919. [13] The simulations for 1 were performed according to the published procedure [12] with a temperature parameter of 303 K and 2 x lo6 macro steps. Maximum step lengths were 20" ($), 20" ($). 25' (w), and 2.5" (T = C1'-01'-C6), leading to an overall acceptance ratio of 0.48.