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ChemInform Abstract: A New Ferrocene in the Asymmetric Addition of Diethylzinc to Aldehydes.

โœ Scribed by C. BOLM; K. MUNIZ FERNANDEZ; A. SEGER; G. RAABE


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dramatic Temperatur
โœ Huichang Zhang; Kin Shing Chan ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

Dramatic Temperature Effect in Asymmetric Catalysis in the Enantioselective Addition of Diethylzinc to Aldehydes. -The enantioselectivity of the addition of Et 2 Zn to aryl aldehydes in the presence of catalytic amounts of a chiral pyridyl-phenol ((S)-MPBP) is found to depend heavily on temperature