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A new assignment of the raman spectrum of tetracyanoethylene anion dimer, (TCNE−)2

✍ Scribed by K.H. Michaelian; K.E. Rieckhoff; E.M. Viogt

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
237 KB
Volume
99
Category
Article
ISSN
0009-2614

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✦ Synopsis

Reccnrl) published resonance Raman data for (TCNE-.-)z in ethanol arc reassigned in light of earlier results for neutral or complexed TCINE and for (TCNC-)2 in ?-methyltetrahydrofursn.

Counterion and solvent influence arc discussed.

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Resonance Raman spectrum of the transien
Resonance Raman spectrum of the transient (SCN)−2 free radical anion
✍ R. Wilbrandt; N.H. Jensen; P. Pagsberg; A.H. Sillesen; K.B. Hansen; R.E. Hester 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 435 KB

The resonance Raman spectrum of the transient species (.krnax = 475 run, ~r,z = 1.6 & formed by pulse radiolysis of aqueous solutions of thiccyanate, SCN2-, IS reported. The spectrum is discussed in terms of the previous assignment of this tzmsient to the radicai anion, (SO@. The observed viiration