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Resonance Raman spectrum of the transient (SCN)−2 free radical anion

✍ Scribed by R. Wilbrandt; N.H. Jensen; P. Pagsberg; A.H. Sillesen; K.B. Hansen; R.E. Hester

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
435 KB
Volume
60
Category
Article
ISSN
0009-2614

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✦ Synopsis

The resonance Raman spectrum of the transient species (.krnax = 475 run, ~r,z = 1.6 & formed by pulse radiolysis of aqueous solutions of thiccyanate, SCN2-, IS reported. The spectrum is discussed in terms of the previous assignment of this tzmsient to the radicai anion, (SO@.

The observed viirational frequencies of the radical anion are consistent with substantial weakenin= of the S-S and the C=N bonds as compared with neutral thiocyanogen.

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Electron spin resonance spectrum of the
Electron spin resonance spectrum of the diphenylcyclobutene anion radical
✍ Ira B. Goldberg 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 330 KB

## Abstract The anion radical of 1,2‐diphenylcyclobutene was studied by electron spin resonance. The hyperfine splittings were found to be 0·47 and 0·74 G for the __meta__‐positions, 2·23 and 2·69 G for the __ortho__‐positions and 4·21 G for the __para__‐positions of the phenyl rings. The methylene