Resonance Raman spectra of the TCNE radical anion dimer in ethanol
β Scribed by Susumu Matsuzaki; Tetsuya Mitsuishi; Koichi Toyoda
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 259 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0009-2614
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Reccnrl) published resonance Raman data for (TCNE-.-)z in ethanol arc reassigned in light of earlier results for neutral or complexed TCINE and for (TCNC-)2 in ?-methyltetrahydrofursn. Counterion and solvent influence arc discussed.
Resonance Raman spectra of p-benzosemiquinone radical anion excited in the 340-430 nm region are reported. Prominent bands, which are not present in the 430 nm spectrum, arc observed at t472 and 127 I cm-' in the 370 nm spectrum. These bands arc attributed to the non-totally symmetric (b,,) modes, v