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A new aspect of the high-field NMR application of Mosher's method. The absolute configuration of marine triterpene sipholenol A

โœ Scribed by Ohtani, Ikuko; Kusumi, Takenori; Kashman, Yoel; Kakisawa, Hiroshi


Book ID
121256166
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
400 KB
Volume
56
Category
Article
ISSN
0022-3263

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High-field FT NMR application of Mosher'
โœ Ohtani, Ikuko; Kusumi, Takenori; Kashman, Yoel; Kakisawa, Hiroshi ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 613 KB

Mosher's (IH) method to elucidate the absolute configuration of secondary alcohols was reexamined by use of high-field FT NMR spectroscopy, which enables assignment of most of the protons of complex molecules. There is a systematic arrangement of Ab (bs -8,) values obtained for the (R)-and (S)-MTPA