A Novel Application of Mosher's Method to Epimeric Carbinols in Acetogenins; Absolute Configurations of 12-Hydroxy-Bullatacins A and B, New Acetogenins from

Applying Mosher's method to acetogenins

Applying Mosher's method to acetogenins bearing vicinal diols. The absolute configurations of muricatetrocin C and rollidecins A and B, new bioactive acetogenins from Rollinia mucosa

✍ Guoen Shi; Zhe-ming Gu; Kan He; Karl V. Wood; Lu Zeng; Qing Ye; John M. MacDouga 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 588 KB

Muricatetrocin C (l), rollidecin A (2), and rollidecin B (3), three new bioactive annonaceous acetogenins bearing vicinal diols, were isolated from the leaves of Rollinia mucosa (Annonaceae) using activity-directed fractionation. The total structural elucidations of 1-3, including the absolute stere