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Determination of the absolute configuration of a tetracyclic drimane sesquiterpenoid by Mosher's method

โœ Scribed by Robert Velten; Wolfgang Steglich; Timm Anke


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
222 KB
Volume
5
Category
Article
ISSN
0957-4166

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โœฆ Synopsis


The high field NMR application of the Moshr method has been succes&Uy applied to determine the absolute c.o&uation of a tstrrcyclic dihydroxydrimane derivative. l%e result


๐Ÿ“œ SIMILAR VOLUMES


Assignment of absolute configuration of
โœ Chuan-Qing Kang; Hai-Quan Guo; Xue-Peng Qiu; Xiao-Li Bai; Hai-Bo Yao; Lian-Xun G ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 148 KB

## Abstract A general procedure to determine the absolute configuration of cyclic secondary amines with Mosher's NMR method is demonstrated, with assignment of absolute configuration of isoanabasine as an example. Each Mosher amide can adopt two stable conformations (named rotamers) caused by hinde