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A new approach to the synthesis of phosphotriester intermediates of nucleosides and nucleic acids

✍ Scribed by G. van der Marel; C.A.A. van Boeckel; G. Wille; J.H. van Boom

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
279 KB
Volume
22
Category
Article
ISSN
0040-4039

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Phosphotriester approach to oligothymidy
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✍ Mitsuo Sekine; Jun-ichi Matsuzaki; Tsujiaki Hata πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 247 KB

DMTrTp(SPh)2 was proposed as a simplest "nucleotide unit" for the synthesis of olygothymidylates. Onephenylthio group was removed selectivelyandrapidly from dithiol-estersby1M pyridinium hypophosphonate. Two kinds of arenedisulfonyl chlorides were newly preparedandutilized as promising condensing a