𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new approach to the synthesis of functionalized 1-alkenyl-1H-1,2,3-triazoles

✍ Scribed by Dorota Sikora; Tadeusz Gajda

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
544 KB
Volume
54
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis

~bstiuctz The Homer-Wadsworth-Emmons (HWE) olefination of l-[(dietboxyphosphoryl)methyl]-4,5-bis(methoxycarbonyl> lH-1,2,3-triazole and l-[(diethoxyphosphoryl)metbyl]-Sphenyl-1 H-1,2,3triazole by means of aldehydes was found to be a convenient method for the preparation of functionalized 1-alkenyl-lH-1,2,3-triazoles in moderate to good yields and low Z/E stereoselectivity.

📜 SIMILAR VOLUMES

A Novel ‘Domino-Click Approach’ to Unsym
A Novel ‘Domino-Click Approach’ to Unsymmetrical Bis-1H-1,2,3-triazoles
✍ Abid H. Banday; Bhupinder S. Arora; Mohammed S. Alam; Halmuthur M. Sampath Kumar 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 203 KB

## Abstract Aryl azides **1** were treated with allenylmagnesium bromide (**2**) to generate 1,5‐disubstituted butynyl‐1__H__‐1,2,3‐triazoles **3** in a domino fashion, which upon Cu^I^‐catalyzed 1,3‐dipolar cycloaddition with aryl azides **4** afforded novel bis‐1__H__‐1,2,3‐triazoles **5** in qua

One-Pot Three-Component Synthesis of Hig
One-Pot Three-Component Synthesis of Highly Functionalized 2,3-Dihydro-1,3-dioxo-1H,5H-pyrazolo[1,2-a][1,2,4]triazoles
✍ Mehdi Adib; Mohammad Hosein Sayahi; Niusha Mahmoodi; Hamid Reza Bijanzadeh 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 69 KB 👁 1 views

## Abstract The reactive 1 : 1 zwitterionic intermediate formed by the addition of isocyanides to dialkyl acetylenedicarboxylates was trapped with 4‐arylurazoles to produce the highly functionalized pyrazolo[1,2‐__a__][1,2,4]triazoles **5** in good yields (__Table__). The structures of the products