The absolute configurations of chiral primary amines can be determined using the optical rotations of the corresponding N-p-toluenesulfonyl-N-2,4-dinitrobenzensulfenyl derivatives. Kinetic asymmetric induction has been used as the basis for numerous methods for the determination of absolute and rel
β¦ LIBER β¦
A new approach to the determination of absolute configuration
β Scribed by Jones, W.
- Book ID
- 109725703
- Publisher
- Nature Publishing Group
- Year
- 1982
- Tongue
- English
- Weight
- 308 KB
- Volume
- 296
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/296011a0
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## Resolution of pentahelicene (4) was recently described['! We have now succeeded in the first allocation of absolute configuration to a helicene, namely to (+ )-( 4). The fundamental investigations of Mislow et al. ['], later confirmed by X-ray structure analysis[31, have shown that
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