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A new approach to 3β, 11α, 15α-trihydroxy-5α-cholestan-7-one, a key intermediate in the synthesis of the steroidal moiety of oogoniols

✍ Scribed by Anastasia, Mario; Fiecchi, Alberto; Gariboldi, Pierluigi; Scala, Antonio


Book ID
126167270
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
399 KB
Volume
44
Category
Article
ISSN
0022-3263

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Crystal structure of 3β-benzoyloxy-6α-ch
✍ David K. Wilson; William K. Wilson; Florante A. Quiocho; George J. Schroepfer Jr 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 441 KB

The X-ray crystal structure of 3~-benzoyloxy-6a-chloro-5a-cholest-7-ene (IV) was determined by the heavy atom method and ref'med to R ---0.063 (space group P2s, a --11.364, b = 11.089, c --12.232,/~ = 99.43 °, Z ---2). IV was previously shown to be an important intermediate in the acid-catalyzed iso