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A NEW AND SELECTIVE METHOD OF OXIDATION

✍ Scribed by Kornblum, Nathan; Powers, Jack W.; Anderson, George J.; Jones, Willard J.; Larson, Harold O.; Levand, Oscar; Weaver, William M.

Book ID
111985229
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
153 KB
Volume
79
Category
Article
ISSN
0002-7863

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Fluorination of 1,3-diketones and b-ketoesters with trifluoroamine oxide in the presence of tetrabutylammonium hydroxide (TBAH) provides a one step route to mono-and difluoro-products selectively fluorinated at the a-position in good yields.