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Reactions of trifluoroamine oxide: a new method for selective fluorination of 1,3-diketones and β-ketoesters

✍ Scribed by Om D Gupta; Jean'ne M Shreeve

Book ID
104253331
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
88 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Fluorination of 1,3-diketones and b-ketoesters with trifluoroamine oxide in the presence of tetrabutylammonium hydroxide (TBAH) provides a one step route to mono-and difluoro-products selectively fluorinated at the a-position in good yields.

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