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A new aldol reaction via cerium enolates

✍ Scribed by Tsuneo Imamoto; Tetsuo Kusumoto; Masataka Yokoyama

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
235 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cerium enolates formed from cerium (III) chloride and lithium enolates undergo aldol reaction with ketones or sterically crowded aldehydes to afford the corresponding R-hydroxyketones in high yields.

Although much progress has been made in the cross-aldol reaction of various metal enolates with aldehydes, 1,2) the analogous coupling between two different

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