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Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction

✍ Scribed by Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima


Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
114 KB
Volume
49
Category
Article
ISSN
0040-4039

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Generation of stannyl derivatives of met
✍ Hirokazu Urabe; Isao Kuwajima πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 199 KB

a-Stannyl derivatives of methyl ketones could be generated from the corresponding silyl enol ethers via a selective silyl/stannyl exchange and were used to prepare aldol products with almost complete regio-and chemo-selectivity. e-Trialkylstannyl ketones and their tautomeric tin enolates are versati