𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new addition reaction of trialkyl phosphite and alkyl halide to nitrone

✍ Scribed by Yoshimi Yamada; Kunio Mukai


Book ID
104216432
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
227 KB
Volume
29
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


N-Substituted l-(alkoxyamino)alkylphosphonates were obtained by a new addition reaction of trialkyl phosphite and alkyl halide to nitrone. A push-pull type mechanism was suggested for the addition reaction.

Nitrones have attracted many chemists because of their versatile reactivities. 1 And the synthetic utility of nitrone has been widely recognized especially in their 1,3-dipolar addition reactions. 2 Addition


πŸ“œ SIMILAR VOLUMES


Nucleophilic Addition of Nitrones to Ket
✍ Anders BΓΈgevig; Kurt V. Gothelf; Karl Anker JΓΈrgensen πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 210 KB πŸ‘ 2 views

A new organic reaction has been discovered in which nitrones react with carbonyl compounds in an aldoltype reaction to give functionalized beta-hydroxynitrones. The alpha-carbon atom of the nitrone undergoes a nucleophilic addition reaction to electron-deficient ketones, such as alpha-ketoesters, al