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A molecular orbital study of the trans influence and kinetic trans effect in square-planar platinum(II) complexes

✍ Scribed by Zumdahl, Steven S.; Drago, Russell S.


Book ID
126992958
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
889 KB
Volume
90
Category
Article
ISSN
0002-7863

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The trans effect in square-planar platin
✍ Zdenek Chval; Miroslav Sip; Jaroslav V. Burda πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 319 KB πŸ‘ 1 views

## Abstract The mechanism of substitution water exchange reactions in square planar trans‐Pt[(NH~3~)~2~T(H~2~O)]^n+^ complexes is studied (Tο£ΎH~2~O, NH~3~, OH^βˆ’^, F^βˆ’^, Cl^βˆ’^, Br^βˆ’^, H~2~S, CH~3~S^βˆ’^, SCN^βˆ’^, CN^βˆ’^, PH~3~, CO, CH~3~^βˆ’^, H^βˆ’^, C~2~H~4~). The trans effect is explained in terms of σ‐do